ISSN 2394-5125
 

Research Article 


TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill.

Abstract
Transport behaviour of copper(I) electrolytes i.e. [Cu(AN)4]2SO4, [Cu(BN)4]2SO4 [Cu(DMphen)2]2SO4 [Cu(Phen)2]2SO4 [Cu(Bipy)2]2SO4 [Cu(TU)4]2SO4 have been studied in the concentration range (4-100) x 10-4 mol dm-3 in DMSO+DMA& DMSO+DMF binary solvent mixtures containing 0, 20, 40, 60, 80, 100 mol% DMA& DMF respectively at 298K by conductance measurements. Bu4NBPh4, Bu4NClO4 were used as “reference electrolyte” and were used to estimate the ionic contributions to the limiting molar conductance values for the copper electrolytes. Various Parameters like limiting molar conductance (É…0), association distance (R), stokes radii (ri), Walden product have been calculated using molar conductance data. It is evident from the stokes radii values that the ion solvation increases in the order DMA >DMF>DMSO indicating strong solvation in case of DMA than DMF than DMSO. The above trend was further supported by Walden product values indicating more solvation in case of DMA> DMF>DMSO.

Key words: Limiting molar conductance/ Preferential solvation/ Solvated radii/ Walden product


 
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How to Cite this Article
Pubmed Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. JCR. 2020; 7(10): 432-439. doi:10.31838/jcr.07.10.91


Web Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. http://www.jcreview.com/?mno=114547 [Access: August 17, 2021]. doi:10.31838/jcr.07.10.91


AMA (American Medical Association) Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. JCR. 2020; 7(10): 432-439. doi:10.31838/jcr.07.10.91



Vancouver/ICMJE Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. JCR. (2020), [cited August 17, 2021]; 7(10): 432-439. doi:10.31838/jcr.07.10.91



Harvard Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill (2020) TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. JCR, 7 (10), 432-439. doi:10.31838/jcr.07.10.91



Turabian Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. 2020. TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. Journal of Critical Reviews, 7 (10), 432-439. doi:10.31838/jcr.07.10.91



Chicago Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. "TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.." Journal of Critical Reviews 7 (2020), 432-439. doi:10.31838/jcr.07.10.91



MLA (The Modern Language Association) Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill. "TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.." Journal of Critical Reviews 7.10 (2020), 432-439. Print. doi:10.31838/jcr.07.10.91



APA (American Psychological Association) Style

Veneeta, Vivek Pathania, B.K Vermani, Manpreet Kaur, Dip Singh Gill (2020) TRANSPORT STUDIES OF SOME COPPER(I) SULPHATE COMPLEXES USING MOLAR CONDUCTANCE MEASUREMENTS IN BINARY MIXTURES OF NON-AQUEOUS SOLVENTS AT 298K.. Journal of Critical Reviews, 7 (10), 432-439. doi:10.31838/jcr.07.10.91